Peroxydes d'Ester

tert-Butyl peroxy-2-éthylhexanoate (TBPEH)

CAS 3006-82-4 · Fabricant et fournisseur de peroxydes organiques en Chine

CAS 3006-82-4UN 3113
N° CAS
3006-82-4
Formule
C₁₂H₁₄O₃
Poids Mol.
216.4
N° ONU
3113
tert-Butyl peroxy-2-éthylhexanoate (TBPEH)

Propriétés Physiques

ApparenceColorless to pale yellow liquid
Oxygène Actif≥7.35%
TDAA35℃
Temp. Dangereuse25℃
Temp. de Stockage20℃

Données de Demi-Vie

1 hour100℃
10 hours73℃

Produits de Décomposition: tert-butyl alcohol, methane, 2-ethyl acid, n-heptane, ethane, carbon dioxide

Aliases & Synonyms

Other names
tert-butyl peroxy-2-ethylhexanoate · TBPEH
Also supplied under these brand names*
Trigonox 21 · Lupersol PDO(Commercial Reference)*

* Brand names are trademarks of their respective owners and are referenced for identification purposes only. LAAP products are not manufactured or endorsed by these companies.

Guide Technique de Sélection

Présentation du Produit

tert-Butyl peroxy-2-ethylhexanoate (TBPEH, CAS 3006-82-4) is a medium-temperature peroxyester with 7.35% minimum active oxygen and a 10-hour half-life temperature of 73°C. It is one of the most widely used low-to-mid temperature initiators for acrylic, styrenic and (meth)acrylate polymerization, and for the curing of unsaturated polyester and vinyl ester resins.

Profil de Demi-Vie et de Température

TBPEH's 10-hour half-life of 73℃ and 1-hour value of 100℃ place its process window at roughly 90-130°C. It is a frequent choice for the mid-section of a multi-initiator cascade in LDPE and PVC processes, where a fast initiator starts the reaction and TBPEH carries it through the peak. Because the decomposition products include 2-ethylhexanoic acid and carbon dioxide, venting and devolatilization design matter when TBPEH is used at high loading.

Sélection au Sein de la Même Famille

In the LAAP peroxyester family, TBPEH (73°C) is the low-temperature workhorse; TBPMH (CAS 13122-18-4, 94°C) and TBPA (CAS 107-71-1, 100°C) are progressively higher-temperature options, and TBPB (CAS 614-45-9, 103°C) is the highest of the group. Choose TBPEH when the process target is 90-130°C; step up to TBPMH or TBPA when you need the initiator to survive a hotter melt or a longer residence time. TBPEH is also the standard choice where a liquid, easily metered initiator is preferred over a solid.

Qualité, REACH et Documentation

Standard TBPEH is a colourless to pale yellow liquid, ≥97% pure, with a colour specification of 20 APHA and an activation energy of 124.9 kJ/mol. Typical controls are assay, active oxygen, colour and water content. Each batch ships with a CoA; REACH-compliant SDS and a TDS with the half-life table are available.

Conditionnement, MOQ et Délai

Standard packing is 20 kg polyethylene drums, with custom sizes on request. SADT is 35°C and the recommended storage temperature is 20°C, so TBPEH is one of the products that genuinely requires cold-chain logistics — it should never be stored above 25°C. Minimum order quantity starts at 25 kg, and quotations are returned within 24 hours.

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